Search results for "ethylenediammonium dichloride"

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CCDC 141923: Experimental Crystal Structure Determination

2001

Related Article: M.Bujak, L.Sikorska, J.Zaleski|2000|Z.Anorg.Allg.Chem.|626|2535|doi:10.1002/1521-3749(200012)626:12<2535::AID-ZAAC2535>3.0.CO;2-U

Space GroupCrystallographyCrystal SystemCrystal StructureEthylenediammonium dichlorideCell ParametersExperimental 3D Coordinates
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Structure and phase transitions in ethylenediammonium dichloride and its salts with antimony trichloride

2000

During the mixing of ethylenediammonium dichloride and antimony trichloride except of reported earlier [NH3(CH2)2NH3]5(Sb2Cl11)2 · 4 H2O a new salt [NH3(CH2)2NH3](SbCl4)2 was obtained. The crystals are monoclinic at 295 K, space group C2/m, a = 13.829(3), b = 7.408(1), c = 7.588(2) Å; β = 103.18(3)°; V = 756.9(3) Å3; Z = 2; dc = 2.585, dm = 2.56(2) g · cm–3. The structure consists of anionic sublattice built of Sb2Cl82– units composed of two SbCl52– square pyramids connected by edge. The ethylenediammonium cations are located in anionic cavities. The cations are disordered. Each methylene carbon atom is split between two positions. The X‐ray diffraction, DSC, TGA and dilatometric methods we…

crystal structuresantimonyethylenediammonium dichloridephase transitionsZeitschrift für Anorganische und Allgemeine Chemie (ZAAC)
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